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We present an analysis of CO rovibrational emission lines in the 183 infrared spectra of nearby Class II objects obtained with the NIRSPEC instrument on the Keck II telescope over the past two decades. The sample includes a broad range of stellar mass (both T Tauri and Herbig Ae/Be) and disk evolutionary states (from full to debris disks). We find that 53% of the sample has CO rovibrational emission lines present in their spectrum with disk/stellar subtype detection rates of 82% for transition disks, 61% for Herbigs, and 77% for classical T Tauri stars. Although there is no discernible difference between T Tauri and Herbig Ae/Be star CO detection rates, the detection of accretion and of CO are statistically correlated in T Tauri stars but not in Herbig Ae/Be objects. Within the sample of T Tauri stars, we find that no weak-line T Tauri stars have CO rovibrational emission lines. We use slab modeling to analyze the density, temperature, and emitting area of the sample. The retrieval results imply that Herbig Ae/Be objects tend to have cooler and larger CO emitting regions than T Tauri stars. We find that the CO emitting area is not a thin ring as defined by temperature, but a ring of varying size, likely dependent on the structure of the disk. We also present guidelines on how to approach CO rovibrational emission lines in JWST spectra and present methods for linking ground-based observations with JWST spectra. This includes line-to-continuum ratio estimates based on stellar mass and accretion rate. 

Abstract Chemical models and experiments indicate that interstellar dust grains and their ice mantles play an important role in the production of complex organic molecules (COMs). To date, the most complex solid-phase molecule detected with certainty in the interstellar medium is methanol, but the James Webb Space Telescope (JWST) may be able to identify still larger organic species. In this study, we use a coupled chemodynamical model to predict new candidate species for JWST detection toward the young star-forming core Cha-MMS1, combining the gas–grain chemical kinetic code MAGICKAL with a 1D radiative hydrodynamics simulation using Athena++ . With this model, the relative abundances of the main ice constituents with respect to water toward the core center match well with typical observational values, providing a firm basis to explore the ice chemistry. Six oxygen-bearing COMs (ethanol, dimethyl ether, acetaldehyde, methyl formate, methoxy methanol, and acetic acid), as well as formic acid, show abundances as high as, or exceeding, 0.01% with respect to water ice. Based on the modeled ice composition, the infrared spectrum is synthesized to diagnose the detectability of the new ice species. The contribution of COMs to IR absorption bands is minor compared to the main ice constituents, and the identification of COM ice toward the core center of Cha-MMS1 with the JWST NIRCAM/Wide Field Slitless Spectroscopy (2.4–5.0 μ m) may be unlikely. However, MIRI observations (5–28 μ m) toward COM-rich environments where solid-phase COM abundances exceed 1% with respect to the column density of water ice might reveal the distinctive ice features of COMs.